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Post by Deleted on Aug 17, 2016 5:51:04 GMT -8
Crystallite: Polycrystalline or multicrystalline materials, or polycrystals are solids that are composed of many crystallites of varying size and orientation. Crystallites are also referred to as grains. Most inorganic solids are polycrystalline, including all common metals, many ceramics, rocks and ice. en.wikipedia.org/wiki/CrystalliteGrain boundary: A grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are defects in the crystal structure, and tend to decrease the electrical and thermal conductivity of the material. Grain boundaries disrupt the motion of dislocations through a material, so reducing crystallite size is a common way to improve mechanical strength, as described by the Hall–Petch relationship. en.wikipedia.org/wiki/Grain_boundary#Boundary_energyIn metal alloys the (electrical) thermal conductivity is inversely proportional to the number of grain boundaries, as crossing a boundary requires an additional small amount of energy. In analog form, this applies to other materials too, as well for particles in granular materials. Amorphous and glassy materials, on the other hand, have no definite structure, but bear similarities with very finely grained polycrystalline or multicrystalline materials. With respect to strength and thermal conductivity fine polycrystalline or amorphous sand eg. slag not larger than 0.2-0.3 mm is quite obviously the best choice. Small amounts of clay can be used to increase porosity by increasing the water demand. A geopolymer binder can easily fulfill the requirement for an aerogel.
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Post by Deleted on Aug 22, 2016 2:52:01 GMT -8
If you want to have an even lower thermal conductivity without the risk of cracking of a one step high water content geopolymer, but a higher strength than it would be possible with perlite, vermiculite or whatever else make your own special aggregate.
Simply make a mixture with an higher amount of liquid and cure it until it gets solid, but not to hard to break it down easily. Break it down to pieces of the desired aggregate size and let the pieces harden completely.
Add the pieces to a new geopolymer mixture.
To minimize the work in the first step cast it to plates with the thickness of the desired aggregate size.
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Post by esbjornaneer on Jan 26, 2018 5:17:07 GMT -8
@karl if the aggregate size ideally is 0-0.2mm (is that the size you would aim for with this aggregate?) how would one guarentee that thickness when pouring the high water content geopolymer? Would you cruch it up in your hands or how would you break the sheet/slab into the best dimentions in the other two directions?
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Post by Deleted on Jan 26, 2018 6:34:49 GMT -8
The 0.2-0.3 mm are for dense aggregates. Pieces of high water content geopolymer could be much larger.
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Post by esbjornaneer on Jan 26, 2018 6:43:44 GMT -8
Any recommendations at all or is it up to us to experiment?
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Post by Deleted on Jan 26, 2018 7:24:56 GMT -8
I have made a few tests to see if it works but not enough to gain more insight.
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